| Advances synthesis process of TNAZ |
|
|
| 분자화약 TNAZ 합성에 대한 개선 기법 |
|
전용구 |
|
국방과학연구소 |
|
|
| Abstract |
|
TNAZ is a high explosive material because it is a highly strained ring compound containing one nitramine and gem dinditro groups. 1-t-butyl-3-nitroazetidine which was used as an intermediate previously, which declined the overall yield in synthesizing TNAZ. We obtained 1-t-butyl-3-hydroxymethyl-3-nitroazetidine in 64% yield from advances process which was used in synthesis of 1-t-butyl-3-nitroazetidine. The reaction pathway, shortening of reaction time, together with improvement of yield were studied too. We have obtained TNAZ in 85% yield. |
| Key Words:
High energy material, 1,3,3-Trinitroazetidine(TNAE), 1-t-Butylamino-3-chloro-2-propanol, 1-t-Butyl-3-hydroxyazetidine hydrochloride, 1-t-Butyl-3-methanesulfonyazetidine, 1-t-Butyl-3,3-dinitroazetidine, oxidative nitration |
|
PDF Links
Full text via DOI
Download Citation
