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J. KIMS Technol > Volume 19(3); 2016 > Article
Journal of the Korea Institute of Military Science and Technology 2016;19(3):319-329.
DOI: https://doi.org/10.9766/KIMST.2016.19.3.319   
Polynigrogen Energetic Materials
Junwung Lee
ReSEAT Team, Korea Institute of Science and Technology Information
폴리나이트로젠 에너지물질
이준웅
한국과학기술정보연구원, ReSEAT 사업팀
Abstract
Current research trends of prediction of possible structures, synthesis and explosive characteristics of polynitrogen molecules(PNs) are reviewed. Theoretically PNs are composed only of nitrogen atoms, in which N-N bonds are either single or double bonds, and thus when these molecules decompose, release of enormous energy is accompanied. From the middle of 20th century energetic material chemists have been seeking possible structures and the methods of synthesis of these new materials. As a results, from $N_4$ to $N_{60}$ together with their ions are predicted, and experimental chemists have been trying to synthesize these materials with a few success, including the famous ${N_5}^+$ ion in 1999. Although experimental successes are very rare beyond $N_5$ until today, the author believes that renovative ideas together with sincere efforts will bring someday next generation of high energy materials such as nitrogen fullerene($N_{60}$) in reality.
Key Words: Polynitrogen, Energetic Materials, Prediction of Structures, Heat of Formation, Explosive Performance
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