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J. KIMS Technol > Volume 18(6); 2015 > Article
Journal of the Korea Institute of Military Science and Technology 2015;18(6):736-742.
DOI: https://doi.org/10.9766/KIMST.2015.18.6.736   
High Pressure Effects on 1,3-Dipolar Cycloaddition of Azides with Alkynes
Jinju Kwon
The 4th Research and Development Institute, Agency for Defense Development
아자이드와 알킨의 1,3-쌍극자 고리첨가반응에서 고압이 반응속도에 미치는 영향에 대한 연구
권진주
국방과학연구소 제4기술연구본부
Abstract
The effect of pressure on 1,3-dipolar cycloaddtion has been studied by means of FT-IR and NMR spectroscopy. Pressure accelerates 1,3-dipolar cycloaddition without solvent or catalyst. This simple and inexpensive method eliminates the need for work-up or purification. The method is expected to be applied to the synthesis of binders for solid rocket propellants.
Key Words: 1,3-Dipolar Cycloaddtion, 1,2,3-Triazole, High Pressure, Solid Rocket Propellant
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